Pass the API ICP Programs API-571 Questions and answers with CertsForce

As per API RP 571 Section 5.3.2.2 (Sigma Phase Embrittlement):

“Sigma phase embrittlement occurs in austenitic stainless steels (like 300 series) and duplex stainless steels exposed to 1000°F to 1800°F (540°C to 980°C)... This embrittlement results in a significant loss of toughness and ductility.”

Sigma phase is not a concern in Monel (nickel-copper alloy) or 5Cr steels.

400 series are ferritic and not typically affected by sigma phase.

Hence, Option A (300 series stainless steel) is correct.

According to API RP 571, under Oxidation:

“Austenitic stainless steels (300 Series) are generally used for oxidation resistance up to about 1500°F (815°C). At higher temperatures, scaling and loss of protective chromium oxide layers increase.”

“Above these temperatures, specialized high-temperature alloys may be required.”

(Reference: API RP 571, Section 5.1.1 – Oxidation)

Therefore, option C is the correct answer.

API RP 571 under Oxidation:

“Carbon steels and low alloy steels, such as 9 Cr, have poor oxidation resistance at temperatures above 1000°F (540°C), rapidly losing thickness.”

“Stainless steels with higher Cr and Ni content (like 310) have superior oxidation resistance.”

Thus, 9 Cr steel will corrode fastest at 1350°F, making option D correct.

API RP 571 on Oxidation indicates:

“Oxidation is a surface loss phenomenon that generally results in uniform thinning. Ultrasonic thickness measurements are typically used to monitor metal loss in oxidizing environments.”

“Metallography may be used to confirm oxide scale structure but is not necessary for routine evaluation.”

Hence, option B is the most appropriate standard method.

According to API RP 571, Section 4.2.1.1 – Sulfidation, and also echoed in API RP 939-C, the presence of certain compounds significantly increases sulfidic corrosion:

“Chlorides are known to accelerate sulfidation and other high-temperature corrosion mechanisms by forming low-melting eutectics and breaking down protective scales on alloy surfaces.”

“Chlorine-containing species also interfere with the formation of stable sulfide or oxide scales, leading to more aggressive metal loss.”

Therefore, chlorides are the most critical accelerant among the listed substances in high-temperature sulfur compound environments, making option C correct.

In API RP 571, Carbonate SCC and Alkaline SCC are both discussed under mechanisms that occur in basic (high pH) environments, often with similar contributing conditions and prevention methods. The document highlights:

“Carbonate SCC is considered a subcategory of alkaline stress corrosion cracking. It results from the concentration of alkaline carbonates under thermal insulation or deposits.”

“Both mechanisms involve the same key parameters: elevated temperatures, tensile stress, and high pH solutions.”

(Reference: API RP 571, 3rd Edition, Section 4.2.2.4 and 4.2.2.3)

Because these mechanisms share similar material susceptibility and operating conditions, they are indeed closely related—option B is therefore the accurate and supported answer.

From API RP 571 Section 5.3.2.1 (Creep and Stress Rupture):

“Short-term creep rupture is often associated with localized overheating and results in bulging and thinning, often with a characteristic ‘fish-mouth’ rupture appearance. These failures occur under sustained load in a short time (hours or days), typically in high-temperature service due to a sudden increase in temperature or poor heat distribution.”

Thus, Option B accurately describes the mechanism and visual indications of short-term stress rupture.

API RP 571 – Sulfidation:

“Sulfidation generally results in uniform thinning of iron-based alloys at temperatures above 500°F (260°C).”

“It is classified as a form of general corrosion, although it can be accelerated in turbulent flow areas.”

So, option A is correct.

API RP 571 identifies these parameters as critical to the corrosion rate of carbon and low alloy steels in sour water environments:

“The extent of corrosion in sour water is influenced by pH, H₂S content, temperature, liquid velocity, and oxygen contamination.”

“These factors control the formation and stability of protective iron sulfide layers.”

(Reference: API RP 571, Section 4.3.2.1 – Sour Water Corrosion)

Therefore, the correct answer is A.

API RP 571, under Organic Acid Corrosion, highlights:

“Corrosive organic acids in overhead systems are those that condense at temperatures above the water dew point. These acids condense independently of water and can form highly concentrated corrosive films.”

“When acids condense first, they aggressively corrode carbon steel prior to any water wash mitigation.”

(Reference: API RP 571, Section 4.3.3.9 – Organic Acid Corrosion)

Hence, option D correctly identifies the most aggressive corrosion scenario.