Galvanic corrosion occurs when two dissimilar metals are electrically connected in the presence of an electrolyte such as brackish water or seawater. The rate and severity of galvanic corrosion depend on:

The relative position of the metals on the galvanic series (potential difference)

Area ratio between anode and cathode

Conductivity of the electrolyte

API RP 571 explains:

“The more active (anodic) metal in the galvanic couple corrodes preferentially. The more noble (cathodic) metal is protected.”

“The greater the difference in potential between the two metals, the more aggressive the galvanic reaction.”

“Aluminum is highly anodic compared to steel. In seawater or brackish conditions, aluminum will corrode rapidly when electrically coupled to steel, especially if the aluminum surface area is small relative to the steel.”

(Reference: API RP 571, Section 4.3.5.1 – Galvanic Corrosion)

Referring to the galvanic series presented in your table:

Aluminum is much higher (more anodic) than steel.

This makes aluminum the sacrificial metal in such a pair.

This is not the case for brass-to-nickel or cast iron-to-Ni-Resist, which are much closer together on the galvanic scale.

Therefore, among all the listed pairs, Aluminum coupled to Steel creates the most significant galvanic potential difference and is most likely to result in galvanic corrosion in brackish or seawater service.

Correct Answer: B