CrackMapExec (CME) is the best choice because it supports authenticated enumeration against Active Directory and can retrieve domain configuration information—including password policy details—using valid domain credentials. In the PenTest+ methodology, once a tester has a standard domain account, a common next step is to enumerate domain settings that influence attack feasibility and safety, such as minimum password length, complexity requirements, lockout threshold, lockout duration, and password history. These values directly inform how to build a “policy-aware” custom wordlist and how to tune dictionary or spraying attempts to remain within rules of engagement and avoid triggering lockouts.

Responder is primarily used for LLMNR/NBT-NS poisoning and capturing or relaying authentication on local networks; it does not query AD policy as its main function. Hydra is a login brute-force tool that performs attacks, not policy retrieval. msfvenom is a payload generator used for exploitation and post-exploitation delivery, unrelated to enumerating AD password policy. Therefore, CME is the most appropriate tool to retrieve the password policy for informed dictionary construction.