Pass the API ICP Programs API-571 Questions and answers with CertsForce

API RP 571 provides detailed insights:

“Brittle fracture generally occurs at low temperatures, specifically below the ductile-to-brittle transition temperature as defined by the Charpy impact test.”

“Most carbon and low-alloy steels are ductile above their Charpy transition temperature but may fracture suddenly without ductility below it.”

(Reference: API RP 571, Section 4.2.1.2 – Brittle Fracture)

Hence, option C is correct and technically accurate based on the material behavior curve.

In steam systems, the absence of a steam trap allows condensate to accumulate, which can lead to corrosion from oxygen and carbon dioxide dissolved in the water—a classic case of condensate corrosion.

From API RP 571 Section 5.3.3.1 (Condensate Corrosion):

“If steam lines or equipment like soot blowers do not have proper drainage or steam traps, condensate may accumulate... Corrosion results from the presence of dissolved oxygen and/or carbon dioxide in the condensate.”

Thus, the correct answer is Option D (condensate corrosion).

According to API RP 571 Section 5.1.3.4 (Naphthenic Acid Corrosion - NAC):

“Sulfur can act as an inhibitor to NAC. Where sulfur content in crude is high, a reduction in naphthenic acid corrosion is sometimes observed, especially in certain parts of vacuum and atmospheric units. However, this is not universally reliable, and corrosion can still occur based on local operating conditions and metal temperatures.”

Thus, Option C (Inhibition) is the correct choice, as sulfur can reduce NAC under some conditions.

According to API RP 571, under High Temperature Hydrogen Attack (HTHA):

“HTHA occurs when hydrogen diffuses into steel at elevated temperatures and reacts with carbides in the steel matrix to form methane (CH₄).”

“The methane is unable to diffuse out of the steel and forms internal pressures, leading to fissuring, decarburization, and eventual failure.”

“HTHA typically affects carbon steels and low alloy steels exposed to high temperature hydrogen services, particularly above 400°F (204°C) depending on partial pressure of hydrogen.”

(Reference: API RP 571, Section 4.2.1.3 – High Temperature Hydrogen Attack)

Hence, option D is the correct and technically supported answer.

From API RP 571 Section 5.1.2.5 (Polythionic Acid Stress Corrosion Cracking):

“PTASCC typically occurs on the surface of stainless steels that have been sensitized. Since cracks are open to the surface, liquid penetrant testing (PT) is the most effective detection method.”

Magnetic particle testing is ineffective for non-magnetic materials like austenitic stainless steels.

UT is less effective for fine surface-connected cracks.

Hardness testing is unrelated to detecting cracking.

Thus, Option C (Liquid penetrant testing) is the correct and preferred method for detecting PTASCC.

API RP 751, which governs HF alkylation units, specifies:

“The total residuals of chromium, nickel, and copper in carbon steel used in HF service should be less than 0.15 wt.% to minimize corrosion risk.”

“Higher residuals increase the reactivity and corrosion rate of carbon steel in the presence of HF acid.”

(Reference: API RP 751, Section 5.3 – Materials Specification for HF Units)

Therefore, option A is the correct choice.

API RP 571 under Atmospheric Corrosion notes:

“The highest corrosion rates are typically observed between 80°F and 120°F (27°C–49°C), particularly when relative humidity is high and surfaces are wet from condensation or rain.”

“At higher temperatures, surface dryness generally reduces corrosion activity despite increased reaction kinetics.”

(Reference: API RP 571, Section 4.3.1.3 – Atmospheric Corrosion)

Thus, among the listed temperatures, 175°F is closest to the upper end of the most active corrosion window, making option A the most accurate answer.

From API RP 571 and RP 932-B:

“In hydroprocessing reactor effluent systems, the most common corrosion mechanism is ammonium bisulfide (NH₄HS) corrosion, which forms in the presence of hydrogen sulfide and ammonia.”

“NH₄HS attacks carbon steel aggressively under turbulent flow and at low pH.”

Correct answer is B – ammonium bisulfide corrosion.

API RP 571 on Naphthenic Acid Corrosion (NAC) details:

“NAC is most aggressive in two-phase flow where the shear stress is high, such as in elbows, reducers, and at orifices.”

“High velocity and turbulence in two-phase flow strip protective layers and accelerate corrosion.”

Therefore, option A is the correct and most critical phase.

According to API RP 571:

“Oxidation is the reaction of metal and oxygen to form oxides. It generally occurs in high temperature environments with excess oxygen.”

“Sulfidation is a high temperature corrosion mechanism that occurs due to interaction between sulfur-containing compounds and metal surfaces, forming metal sulfides. Like oxidation, sulfidation occurs in environments above 500 °F (260 °C).”

“Both oxidation and sulfidation can occur concurrently, particularly in mixed environments of oxygen and sulfur.”

(Reference: API RP 571, Sections 5.1.1 and 5.1.3 – Oxidation & Sulfidation)

These two mechanisms are thermally activated and occur in elevated temperature conditions found in heaters, furnaces, and piping systems. Hence, option B is correct.