Enterprise authentication (such as WPA2-Enterprise) utilizes unique credentials for each user, typically integrating with an authentication server like RADIUS. This allows for tracking and logging user activity, ensuring that all connections can be traced back to individual users. PSKs (Pre-Shared Keys) are shared among users and do not provide individual accountability. Captive portals can identify users but are less secure than enterprise authentication, and Wired Equivalent Privacy (WEP) is outdated and not recommended for security purposes.