Aservice control policyattached at the organization root is the right preventive control because SCPs define the maximum permissions for principals in member accounts across the organization. AWS documentation states that SCPs restrict permissions for IAM users and roles in member accounts and that an explicit deny overrides allows from other policies. That makes an SCP the cleanest centralized way to block creation of IAM users and access keys everywhere. Inline user policies would be harder to maintain, and GuardDuty or Config would be detective or corrective controls rather than the preventive control the question asks for.

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