Option C is correct because the requirement is to verify that at least 90% of values in the Email column are valid email addresses. In AWS Glue Data Quality, rules are written in DQDL, and ColumnValues is the rule component used to validate whether column values satisfy a condition or pattern. AWS Glue Data Quality documentation explains that DQDL is the language used to define rules, and it specifically notes that ColumnValues rules can evaluate column content and that NULL values do not pass during comparisons. That is important here because the problem explicitly says the column contains null entries and invalid email values. A threshold of > 0.9 means the rule passes only when more than 90% of rows satisfy the email-validation condition.

Option A is incorrect because Uniqueness checks the percentage of values that are unique, not whether values are valid email addresses. AWS documents Uniqueness as measuring how many values occur exactly once, which is unrelated to email-format validity. Option D has the same issue because UniqueValueRatio addresses uniqueness characteristics, not format validation. Option B uses the right rule family but the wrong threshold because > 0.1 would require only 10% valid values. Therefore, ColumnValues with a threshold greater than 0.9 is the correct choice.